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Dante A. Simonetti

~bio~
-contact-
dasimonetti@wisc.edu
(608) 265-3784
-status-
5th year graduate student
-research area-
Catalytic Bio-Reforming
-hometown-
Massillon, Ohio
-undergraduate-
University of Notre Dame
-publications-
Simonetti, D. A.; Kunkes, E. L.; Dumesic,
J. A.. Gas-phase conversion of glycerol to synthesis gas over
carbon-supported platinum and platinum-rhenium catalysts. Journal of
Catalysis (2007), 247(2), 298-306.
Soares, Ricardo R.; Simonetti, Dante A.;
Dumesic, James A.. Glycerol as a source for fuels and chemicals by
low-temperature catalytic processing. Angewandte Chemie, International
Edition (2006), 45(24), 3982-3985.
J.W. Shabaker,
D.A. Simonetti, R.D. Cortright and J.A. Dumesic. Sn-modified Ni catalysts for
aqueous-phase reforming: Characterization and deactivation studies Journal of
Catalysis, Volume 231, Issue 1, 1 April 2005, Pages 67-76
Suren L. Kharatyan, Hakob A. Chatilyan, Alexander S. Mukasyan, Dante A.
Simonetti, Arvind Varma. Effect of heating rate on kinetics of high-temperature
reactions: Mo-Si system. AIChE Journal. Volume 51, Issue 1, Date: January 2005,
Pages: 261-270
~research summary~
My research involves the catalytic reforming of oxygenated hydrocarbons to fuel
cell grade hydrogen and Fischer-Tropsch synthesis gas. Increasing energy
demands and depleting fossil fuel resources result in the need for alternative
energy sources. Hydrogen fuel cells and coal liquefaction are attractive
options. Steam reforming produces hydrogen along with high amounts of CO and
requires additional energy to vaporize water. Running this reaction in the
aqueous-phase produces hydrogen at very low CO concentrations due to more
favorable water-gas shift thermodyamics. Additionally, less energy is required
since the vaporization of water is no longer necessary. Removing water and
running in the vapor phase leads to a product stream of CO and hydrogen which
can be used as syngas for the Fischer-Tropsch process. My work focuses on the
elucidation, development, and characterization of catalyst for these reactions.
-in
collaboration with-
Mavrikakis
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